7/14/2023 0 Comments Tonight not tonight pillow caseRobert Carlson from the DeKalb County Public Defender’s Office was appointed to represent Doll. He sat in a wheelchair during his virtual appearance from jail.ĭoll will remain held without bond at the DeKalb County Jail until at least Monday, pending a ruling on the DeKalb County State’s Attorney’s Office’s petition to deny bail, Pedersen ordered.Ĭircuit Court Judge Marcy Buick is expected to make a bond ruling during an in-person hearing set for 8:45 a.m. He did not otherwise speak Wednesday during his first court appearance on the charges. “Yes, sir, your honor,” Doll said when Judge Joseph Pedersen asked if he understood the proceedings. DeKalb County court recordsĭoll faces eight charges, including first-degree murder, in Sasso-Cleveland’s death. The witness told police they allegedly heard a female yell “Just give me my phone back, I want to leave,” and “I can’t breathe,” according to a DeKalb Police Department incident report filed in DeKalb County court May 9. ![]() Timothy Doll, 29, is charged with murder in the death of Sasso-Cleveland, 15, of DeKalb. Some of Gracie Sasso-Cleveland's (shown in the picture) friends gathered Monday, May 8, 2023, in the backyard of a home in the 500 block of College Avenue in DeKalb where the girl was allegedly killed on May 4, 2023. The witness told police they allegedly heard a female yell “Just give me my phone back, I want to leave,” and “I can’t breathe,” according to a DeKalb Police Department incident report filed in DeKalb County court Tuesday. Just last month, Doll pleaded guilty to 2020 sex abuse charges involving a minor.Ī witness who also lives in the College Avenue building told police they heard commotion coming from Doll’s apartment the night of May 4, court records state. Doll, of the 500 block of College Avenue, suffocated the girl with a pillow after a fight, before discarding her body and personal belongings, according to DeKalb County court records filed Tuesday. Sasso-Cleveland’s family reported her missing to DeKalb police Saturday and she wasn’t found until Sunday, pronounced dead from asphyxiation, according to the DeKalb County Coroner’s Office. Paramedics arrived the night of May 4, not knowing the 15-year-old girl’s body lay discarded nearby, to take the man accused in her death to a hospital for treatment.
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7/14/2023 0 Comments Big clock photo![]() Through five rounds, a record 12 quarterbacks were selected - the most in the common draft era. Tennessee's Hendon Hooker, who also attracted some late buzz as a possible first-rounder, went early in the third round to the Detroit Lions. Levis, projected by many draft prognosticators as a top-10 pick, fell to the second round, where he was scooped up by the Titans. Led by Young (Panthers), three quarterbacks were taken in the first four picks including Ohio State's Stroud (Texans) and Florida's Richardson (Colts). Some other takeaways from three eventful days in Kansas City:Ī year ago, the Pittsburgh Steelers selected Kenny Pickett as the lone first-round quarterback and the only one selected in the first 73 picks but this time around, a stronger quarterback class rebounded in a big way. Once alone in their post-rebuild success, the Jaguars look to have competition as the rest of the division adds foundational players. ![]() 4 overall.Īnd as for the Tennessee Titans, first-year general manager Ran Carthon made a shrewd move to trade up and snag Kentucky quarterback Will Levis, widely projected to be a first-round pick, with the No. Stroud and Alabama linebacker Will Anderson Jr. The Indianapolis Colts weren't far behind, drafting Florida quarterback Anthony Richardson at No. 3, securing future leaders for first-year head coach DeMeco Ryans on both sides of the ball in Ohio State quarterback C.J. The Houston Texans traded with the Arizona Cardinals to make back-to-back picks at No. 1 picks in 20, but the other three teams made significant moves throughout the 2023 draft to close the gap. The Jacksonville Jaguars won the division in 2022 after back-to-back No. The other thing that's certain now that the draft is over: The AFC South is at the dawn of a new era. 1 by the Carolina Panthers, and everything else would be chaos. Two things were certain heading into the 2023 NFL draft: Bryce Young would be drafted No. NFL, NFL Draft, Pittsburgh Steelers, Tennessee Titans, Arizona Cardinals, Atlanta Falcons, Detroit Lions, Georgia Bulldogs, Philadelphia Eagles, Houston Texans, Indianapolis Colts NFL draft 2023 takeaways: A run on QBs and the rebuilt AFC South 7/14/2023 0 Comments Purple wave![]() ![]() Find high-quality stock photos that you wont find anywhere. ![]() Visit the ‘Purple Wave 2023 supports Manchester’s cancer research’ JustGiving pageĬreate your fundraising page by clicking ‘Start fundraising’. Search from 111949 Purple Waves stock photos, pictures and royalty-free images from iStock. Check out this fantastic collection of Purple Wave wallpapers, with 52 Purple Wave background images for your desktop, phone or tablet. Other members of the University community – ‘Community – Manchester’sĬancer research fundraiser’ Once you’ve successfully completed the Purple Wave registration process, you’ll Alumni – ‘Alumni – Manchester’s cancer research fundraiser’ Staff – ‘Staff – Manchester’s cancer research fundraiser’ Student – Manchester’s cancer research fundraiser’ Vector eps 10 illustration purple wave logo stock illustrations Retrowave or synthwave or vaporwave aesthetic illustration of. Since the equipment is located at the owners place of business, not the auction. Purple Wave specializes in liquidating equipment and vehicles through no-reserve public Internet auctions providing the easiest and most straightforward way to buy and sell used equipment quickly and efficiently. Purple Wave is a legitimate auction house, but purchases there can be risky. Make sure you select the appropriate free(!) ticket type: Cancer Fundraiser If you are a member of the University staff, a member of our alumni community, or a friend of the University, select the ‘Public’ option Please select the relevant fee: Purple Wave, the largest no-reserve Internet auction firm in the country, is transforming the way sellers reach buyers to turn assets into cash. Register to take part in the Purple Wave. Purple Wave handles online government surplus auctions for Douglas County, Kansas. 7/14/2023 0 Comments Texpad 2017![]() This one-window design works especially well with OS X 10.7 Lion's fullscreen mode. In even the largest projects all files are accessible from the outline view to the left of the editor. Open a LaTeX root file, and Texpad will scan it, open any referenced files. Texpad's elegant single window design saves you from the clutter of windows. Texpad is a LaTeX editor designed for straightforward navigation, editing and typesetting of projects of any size. Clicking on these errors will direct you to the offending line in the LaTeX source. Additional text editors for macOS include. I would prefer to not have these PDFs actually be stored in my working file directoryit adds clutter. Some other text editors and viewers include Microsoft Word, TextPad, Notepad2, Geany, and Microsoft WordPad. ![]() Texpad replaces LaTeX's obscure console output with a table of typesetting errors. Texpad is a commercial software which costs 24.99. pdf in the same location with the same name. When Texpad opens a document it scans through it, looking for LaTeX structure commands and any included files, then it presents you with an outline view with which you can swiftly navigate the entire project. Follow the prompts to complete the installation. Installed on the user's system.Texpad is a LaTeX editor designed for straightforward navigation of projects of any size. To install TextPad, visit, click the Download tab, and download the 32-bit or 64-bit version as appropriate (Windows only). Textpad calls the TextPad text editor, if this editor is The new version has updated the default version of TextPad from TextPad Version 5 to TextPad Version 8. Texpad 2020 mac is a LaTeX editor designed for straightforward navigation of projects of any size. When Texpad opens a document it scans through it, looking for LaTeX structure commands and any. The textpad package is described as below on my website. Texpad 2017 mac is a LaTeX editor designed for straightforward navigation of projects of any size. In Stata, use the ssc command to do this, or adoupdate if you already have an old version of textpad. CleanTex Texpad Tape Head Cleaner Pads, Box of 80 Pads (CT801) Brand: CleanTex 12 ratings -22 2112 List Price: 27. Windows-compatible systems are preferred so that you may use Textpad as your programming environment, but other systems may also be used as long as you take. ![]() Open a LaTeX root file, and Texpad will scan it, open any referenced files, extract the document structure for display in the outline view, and configure the typesetter according to the packages and tools used by your document. Thanks once again to Kit Baum, a new version of the textpad package is now available for download from SSC. Texpad is a LaTeX editor designed for straightforward navigation, editing and typesetting of projects of any size. 7/14/2023 0 Comments Looney tunes dash game play online![]() ![]() To use this picture as your desktop wallpaper, right-click on it with your mouse and then select "Set as Windows Wallpaper" or "Set as Background", or whatever similar option your particular browser provides in the right-click pop-up menu. Here is a Looney Tunes desktop wallpaper picture (800 x 600 pixels): (including a large collection of images and MP3, QuickTime, WAV and WMV multimedia)Ĭlick here for some Hanna-Barbera online fun and games > Run, jump, smash, and slide into new levels and adventures with Bugs Bunny, Road Runner, Tweety Bird, and other Looney Tunes favorites Complete level objectives to unlock new Looney Tunes. View the "Complete List of Tom and Jerry Cartoons" page > Play the "Tom and Jerry: Refriger-Raiders" game > Also there are no where near enough toon level up potions, even at level 41 to be only rewarded with level 2 potions for quick play is really poor game design. ![]() Play the "Toon Marooned: Protect the Fire" game > Play the "Taz's Tropical Havoc: Twister Island" game > Play the "Daffy Duck: Tricky Duck Volleyball" game > Everything looks so sharp & the colourful worlds really speak volumes. As well as having good controls Looney Tunes Dash also happens to be one of the prettier endless runners on the market. It’s the same controls for every endless runner & they work perfectly fine here. Play the "Daffy Duck: Daffy's Studio Adventure" game > Swipe left to move left, swipe down to slide, swipe up to jump etc. Play the "Sylvester: Attack of the Tweety Zombies" game > Looney Tunes Dash is an Adventure, Endless Runner, and Single-player video game developed and published by Zynga for Android. Play the "Sylvester: Under the Sea" game > 7/13/2023 0 Comments Atlas volkswagen![]() Less impressive, however, are the Atlas' underpowered engines and cheap cabin materials, as well as its relatively short warranty. The Atlas is comfortable and relaxing to drive, and it feels rather agile for an SUV of its size. Volkswagen offers the Atlas in two- and three-row versions, and both impress with generous seating space, expansive cargo areas and easy-to-use tech features. In our luggage testing, the Atlas impressed us by fitting four carry-on suitcases behind the third row and 38 behind the first, same as the enormous Honda Pilot.The 2023 Atlas is a decent option if you're shopping for a midsize SUV. The cabin should accommodate just about anything a suburban family can throw at it, and there are plenty of thoughtfully placed storage nooks to stash small items. The interior design of the Atlas is uncomplicated and utilitarian-perfect for families but less so for style mavens. ![]() Plus, a third row of seats that can comfortably accommodate full-size adults is a definite win. Interior, Comfort, and Cargoįamily-friendly interior space, a straightforward control layout, and an overabundance of cupholders make the Atlas a practical choice, even among other highly practical rivals. ![]() The V-6 Atlas returned 24 mpg, and the four-cylinder model delivered 27 mpg. Both the V-6 and the four-cylinder models bested their EPA ratings on our 200-mile real-world test route. The thirstier V-6 model is rated at 17 mpg city and 23 mpg highway with front-wheel drive and 16 mpg city and 22 mpg highway with all-wheel drive. The four-cylinder model is the most efficient with the front-wheel drive variant scoring ratings of 21 mpg city and 24 mpg highway. The Atlas's fuel-economy ratings aren't groundbreaking for this class of big-box family haulers, but its real-world performance isn't far off from the segment's fuel sippers. Our VW Atlas Has Us Divided at 30K Miles.2021 VW Atlas Gets a New Look and New Features.2021 Atlas SUV Dons a Much Prettier Face.The ride is smooth, and all but the harshest potholes are absorbed. It is composed on the highway and nimble in the city. While it's not as much fun to drive as the Mazda CX-9, the Atlas responds obediently to steering inputs and never feels clumsy. Though the last four-cylinder and V-6 models we tested had ordinary acceleration, out on the road, they rarely felt underpowered. The V-6 feels and sounds refined, transmitting nary a shiver into the cabin. Both pair with an eight-speed automatic transmission and either front- or all-wheel drive. The Atlas comes with one of two engines-a 235-hp four-cylinder or a 276-hp V-6. To that we'd add the second-row captain's chairs and the tow hitch that unlocks the Atlas's maximum towing capacity of 5000 pounds. Our example includes a wide range of contemporary features that include an 8.0-inch touchscreen infotainment system, adaptive cruise control, three-zone climate control, and remote start. Those who want 4Motion all-wheel drive can add it for $1900. Still, we'd recommend the V-6-powered SE with the Technology package. The 2021 Atlas costs slightly more than last year's model. The four-cylinder Atlas is now available with all-wheel drive for the first time. Inside, you'll find a new steering wheel, updated stitching on the seats, an 8.0-inch touchscreen (on SE and SEL models), and the latest iteration of VW's Car-Net smartphone app. Models with the R-Line option come with special badging, a body kit, and 20- or 21-inch rims. A more attractive three-bar grille graces the front end, as do revised headlights that now feature standard LED elements. VW refreshes the 2021 Atlas with new front and rear fascias that increase the SUV's overall length by almost three inches. And the 2021 boasts an array of standard driver assists and confident handling traits, but don't expect the Atlas to be as exciting or sophisticated as this segment's best. A pair of steady albeit staid engines provide motivation with either the front- or all-wheel-drive SUV. VW apparently wanted the Atlas to look and feel like a hospital room, but it offset that sterile aesthetic with loads of desirable features. It's also one of the biggest mid-size crossovers, with a giant footprint that gives way to three spacious rows of seating. The 2021 Volkswagen Atlas has the boxy appearance, cavernous interior, and vast practicality that have defined SUVs for decades. 7/13/2023 0 Comments Backline band myrtle beachMarch 13th-Bear Creek Bluegrass Festival-Locust, NC January 8th-Bill's Pickin' Parlor-Columbia, SC-7pm January 2nd-Jekyll Island Bluegrass Festival-Jekyll Island, GA ![]() November 12th-Palatka Bluegrass Festival-Palatka, FL November 11th-Heading Home Bluegrass Festival-Lyons, GA October 29th-The Bridge Church Fall Festival-Chesnee, SC October 1-Bear Creek Bluegrass Festival-Locust, NC September 24th-Vine Grove Bluegrass Festival-Vine Grove, KY-12pm September 17-Port Royal Concert Series-Port Royal, SC-4pm July 16th-Dacusville Community Center-7pmĪugust 6th-Little Mountain Reunion-Little Mountain, SC-2pmĪugust 20th-NC State Bluegrass Festival-Marion, NC July 15th-Bill's Picking Parlor-Columbia, SC-8pm June 11-Cherokee Bluegrass Festival, Cherokee, NC May 28th-Lil John's Mountain Music Festival-Snow Camp, NC-12pm CANCELLED March 19th-Temple Baptist Church Wild Game Dinner-Anderson SC-1pmĪpril 23rd-Big Lick Bluegrass Festival-Oakboro, NC March 5-Winter Bluegrass Jamboree-Pickens, SC-6pm February 12th-Monica Gossett Benefit-Church at Lake Cooley-Inman SC-6pm November 11th- Palatka Bluegrass Festivalįebruary 4th-Sigal Music Museum-Greenville, SC-7pm November 4th-SEBGMA Bluegrass Concert-Florence, SC September 22nd-Vine Grove Bluegrass Festival-Vine Grove, KY ![]() September 16th- Gospel Revival Concert Liberty Baptist Church, Dawsonville, GA July 29th- Gramling Opry House, Gramling, SC July 21-Bill's Pickin Parlor-Columbia, SC July 1st- Middle Tyger Library Concert- Lyman, SC January 14-WNCW Going across the Mountain Live, Spindale, NCįebruary 18th-Palatka Bluegrass Festival-Īpril 1nd-Toccoa Ritz Bluegrass Festival. April 5th- 2nd Annual Toccoa Bluegrass Festival, Toccoa, GA 7/13/2023 0 Comments Free texting app for android![]() It is so popular that it needs no introduction.Įvery 90s kid has used this app at least once in their teenage years. The Line is one of the most popular texting apps that work over the internet or WIFI. The fifth app on our list is Line, a quite famous messaging app that has changed the idea of communication. KakaoTalk is fast, simple, fun, reliable, and the entire messaging history is stored on Google servers. KakaoTalk allows to create a group of an unlimited number of people for communication and has more than one hundred fifty million existing users. What sets KakaoTalk apart from other apps is its polling and scheduling features. This WIFI texting app has basic features like other apps also, it has some new fun and cool extra features. The fourth app on our list is KakaoTalk, a fun and free WIFI texting app for android devices that connect people worldwide. Without any additional payment and just WIFI or internet, you can use Signal Private Messenger to communicate for free in real-time. Along with encryption, the Signal Private Messenger app also offers disappearing messages features and a lock of screenshots. Of course, both individuals must be a user of this app for encrypted communication. ![]() The encryption of the messages is done via an advanced tool. There’s no sticker, no games, no integration, but just strong encryption. The advanced user interface is solely focused on protecting the messages. Signal Private Messenger is an excellent option for people who love to chat. Signal Private Messenger allows its users to instantly communicate with loved ones over WIFI and the internet. Telegram is very safe, and you won’t lose your personal data because this app doesn’t cooperate with the government and doesn’t sell your data to any 3rd parties, unlike other texting apps. Telegram is free to download on android devices and has an open API.Īlthough Telegram is not end-to-end encrypted, a user can use the secret chat room feature to send secret chats that self-destruct after some time. The second app on our list is quite a popular app loved by millions of people, Telegram, one of the fastest texting apps that work over the internet and WIFI. What makes WhatsApp the best is that it is free and can be accessed by any android user. A user can customize the wallpaper, set custom alerts, etc. Also, WhatsApp Messenger has the feature of a blocklist. The user interface is quite easy and has an automatic end-to-end encryption system. In WhatsApp Messenger, you can chat with up to 256 people at once. It is one of the most accessible ways to text over WIFI. WhatsApp Messenger is quite versatile and has a lot of features. This free messaging app is popular worldwide and is the leader of communication apps. We don’t think that this app needs any introduction. WhatsApp MessengerĪt the first, we have WhatsApp Messenger. 7/13/2023 0 Comments Wedge sandals![]() Start your summer in style with wedge sandals at Shoe Zone. Papillio by Birkenstock Glenda Wedge Sandal (Women) 140.00 Current Price 140.00 (8) New Markdown. Nude wedge sandals are a versatile choice that can be worn. Shop the latest styles from the best brands like Steve Madden, Sam Edelman, Vince Camuto and more. Sofft wedge sandals are designed with comfort in mind, providing support for as long as you need it. Browse a variety of on-trend styles that perfect for every occasion, available in regular and extended sizes. ![]() This cookie enables the user's sessions to be kept open during their visit and allows them to place an order or a whole series of functions such as: date the cookie was added, language selected, currency used, last product category visited, recently viewed products, agreement to use the site's services, customer identifier, connection identifier, surname, first name, logged in status, their encrypted password, e-mail related to the customer's account and the cart identifier. Treat yourself to some womens wedge sandals to add height without compromising on comfort. Free shipping on women's wedge sandals at . Let Dillard's be your destination for women's wedge sandals. The website cannot function properly without these cookies. Wedges and platforms are the perfect shoes to add height without compromising. 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Calculation of solutionstate NMR parameters, including chemical shift values and scalar coupling constants, is often a crucial step for unambiguous structure assignment. (Although Hahn described the effects of diffusion on spin-echoes four years previously, this paper takes the concept a step further). J/2 if spin A Features to notice about J-couplings i. An iNMR document can contain a table of chemical shifts and coupling constants, called J Manager. Effects of diffusion on free precession in nuclear magnetic resonance experiments. Coupling constants will usually, but not always, fall into the shaded band on this graph. NMR measurements of chemical shifts and nuclear quadrupolar coupling. In general, though, a plot of this equation has the shape shown in Figure 1-4. Computational studies have been carried out on a series of silver compounds. of Residual Dipolar Couplings in MR Spectra and Data Analysis of Carnosine. The equation follows the general format of J A + B (cos ) + C (cos 2), with the exact values of A, B and C dependent on several different factors. (The classic paper where the concepts of spin-lattice and spin-spin relaxation are developed formally as well as the recognition of inhomogeneity effects that we now call T2* but which the authors called T2').Ĭarr HY, Purcell EM. Peak splitting due to the residual dipolar coupling (RDC) represents a. Coupling to 2 equivalent deuterium (2H) nuclei (I1) will split the signal into 2x2x1 + 1 5 peaks. In NMR spectroscopy, J -coupling contains information about relative bond distances and angles. J-couplings are also known as scalar couplings. NMR chemical shifts are accurate indicators of molecular environment and have been extensively used as aids in protein structure determination. the protons in a methyl group) will give a multiplet consisting of 2x3x½ + 1 4 peaks. A J-coupling is an interaction between nuclei containing spin. The reason why we use Hertz, is because it's the same coupling constant no matter what NMR spectrometer you're using, so it doesn't matter what the operating. Relaxation effects in nuclear magnetic resonance absorption. Coupling to a single 1H nucleus will split the signal into 2x1x½ + 1 2 peaks. The coupling constant is measured in Hertz, so it turns out to be 1.4 Hz, and if it's 1.4 Hz for this one, it must be 1.4 Hz for this one, because those protons are coupled together. |